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Serial number |
Classification of pollutants |
Maximum allowable emission concentration |
1 |
Total mercury |
0.05 mg/L |
2 |
Alkyl mercury |
No detection |
3 |
Total cadmium |
0.1 mg/L |
4 |
Hexavalent chromium |
0.5 mg/L |
5 |
Total arsenic |
0.5 mg/L |
6 |
Total lead |
1.0 mg/L |
7 |
Total nickel |
1.0 mg/L |
8 |
Total beryllium |
0.005 mg/L |
9 |
Total chromium |
1.5 mg/L |
10 |
Benzo (a) pyrene |
0.00003 mg/L |
11 |
Total silver |
0.5 mg/L |
12 |
totalαradioactivity |
1Bq/L |
13 |
totalβradioactivity |
10Bq/L |
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For the second kind of pollutants, the maximum allowable emission concentration of sampling at the discharge outlet of the pollutant discharge unit shall meet the requirements of Table 2 of this standard.Table 2 maximum allowable emission values of class II pollutants (indicators)
Serial number |
Contaminants |
Scope of application |
First class standard |
Secondary standard |
|||
1 |
PH |
All pollutant discharge units (dimensionless) |
6~9 |
||||
2 |
chroma |
All pollutant discharge units (dilution ratio) |
50 |
80 |
|||
3 |
Suspended solids (SS) |
Chemical fertilizer |
Ammonia industry |
large |
mg/L |
60 |
|
kg/t |
0.6 |
||||||
Small and medium sized |
mg/L |
80 |
|||||
kg/t |
4.0 |
||||||
Ammonium phosphate and heavy superphosphate, nitrophosphate industrial mg / L |
30 |
50 |
|||||
Other pollutant discharge units, mg / L |
70 |
150 |
|||||
Centralized industrial wastewater treatment plant, mg / L |
70 |
150 |
|||||
Other pollutant discharge units, mg / L |
70 |
150 |
|||||
4 |
Five day biochemical oxygen demand (BOD5) |
Petrochemical Industry (including petroleum refining), mg / L |
20 |
30 |
|||
Chemical fertilizer, mg / L |
20 |
30 |
|||||
Inorganic chemical raw materials, mg / L |
20 |
30 |
|||||
Organic chemical raw materials, mg / L |
20 |
30 |
|||||
Pesticide, mg / L |
20 |
30 |
|||||
Polymer, mg / L |
20 |
30 |
|||||
Fine chemicals and others, mg / L |
20 |
30 |
|||||
Centralized industrial wastewater treatment plant, mg / L |
20 |
30 |
|||||
5 |
Chemical oxygen demand (COD) |
Petrochemical Industry (including petroleum refining), mg / L |
60 |
120 |
|||
Chemical fertilizer |
Ammonia industry |
large |
mg/L |
100 |
|||
kg/t |
1.0 |
||||||
Small and medium sized |
mg/L |
120 |
|||||
kg/t |
6.0 |
||||||
Other pollutant discharge units, mg / L |
80 |
120 |
|||||
Inorganic chemical raw materials, mg / L |
80 |
120 |
|||||
Organic chemical raw materials, mg / L |
80 |
120 |
|||||
Pesticide, mg / L |
100 |
120 |
|||||
Polymer, mg / L |
80 |
120 |
|||||
Fine chemicals and others, mg / L |
80 |
120 |
|||||
Centralized industrial wastewater treatment plant mg / L |
80 |
100 |
|||||
|
|
|
|
|
|||
Table 2 (Continued) |
|||||||
6 |
Petroleum |
Chemical fertilizer |
Ammonia industry |
large |
mg/L |
5 |
|
kg/t |
0.05 |
||||||
Small and medium sized |
mg/L |
5 |
|||||
kg/t |
0.25 |
||||||
Other pollutant discharge units |
mg/L |
5 |
10 |
||||
Other pollutant discharge units mg / L |
5 |
10 |
|||||
7 |
Volatile phenol |
Chemical fertilizer |
Ammonia industry |
large |
mg/L |
0.1 |
|
kg/t |
0.001 |
||||||
Small and medium sized |
mg/L |
0.1 |
|||||
kg/t |
0.005 |
||||||
Other pollutant discharge units, mg / L |
0.5 |
||||||
Other pollutant discharge units, mg / L |
0.5 |
||||||
8 |
total cyanide |
Chemical fertilizer |
Ammonia industry |
large |
mg/L |
0.2 |
|
kg/t |
0.002 |
||||||
Small and medium sized |
mg/L |
1.0 |
|||||
kg/t |
0.05 |
||||||
Other pollutant discharge units, mg / L |
0.5 |
||||||
Other pollutant discharge units, mg / L |
0.5 |
||||||
9 |
sulfide |
Chemical fertilizer |
Ammonia industry |
large |
mg/L |
0.50 |
|
kg/t |
0.005 |
||||||
Small and medium sized |
mg/L |
0.50 |
|||||
kg/t |
0.025 |
||||||
Other pollutant discharge units, mg / L |
1.0 |
||||||
Other pollutant discharge units mg / L |
1.0 |
||||||
10 |
Ammonia nitrogen |
Petrochemical Industry (including petroleum refining) mg / L |
15 |
30 |
|||
Chemical fertilizer |
Ammonia industry |
large |
mg/L |
40 |
|||
kg/t |
0.4 |
||||||
Small and medium sized |
mg/L |
60 |
|||||
kg/t |
3.0 |
||||||
Other pollutant discharge units, mg / L |
15 |
25 |
|||||
|
|
|
|
|
|
||
Table 2 (Continued) |
|||||||
10 |
Ammonia nitrogen |
Inorganic chemical raw materials, mg / L |
15 |
25 |
|||
Organic chemical raw materials, mg / L |
15 |
25 |
|||||
Pesticide, mg / L |
15 |
25 |
|||||
Polymer, mg / L |
15 |
25 |
|||||
Fine chemicals and others, mg / L |
15 |
25 |
|||||
Centralized industrial wastewater treatment plant, mg / L |
15 |
25 |
|||||
11 |
fluoride |
All pollutant discharge units, mg / L |
10 |
10 |
|||
12 |
Phosphate (as P) (total phosphorus) |
Petrochemical Industry (including petroleum refining), mg / L |
0.5 |
1.0 |
|||
Chemical fertilizer |
Ammonium phosphate and heavy superphosphate, nitrophosphate industry, mg / L |
20 |
30 |
||||
Other pollutant discharge units, mg / L |
0.5 |
1.0 |
|||||
Inorganic chemical raw materials, mg / L |
0.5 |
1.0 |
|||||
Organic chemical raw materials, mg / L |
0.5 |
1.0 |
|||||
Pesticide, mg / L |
0.5 |
1.0 |
|||||
Polymer, mg / L |
0.5 |
1.0 |
|||||
Fine chemicals and others, mg / L |
0.5 |
1.0 |
|||||
Centralized industrial wastewater treatment plant, mg / L |
0.5 |
1.0 |
|||||
Note: kg / T is the amount of pollutants allowed to be discharged per ton of ammonia production. |
|
|
Test index
In fertilizer production Ammonia nitrogen / nitrate content
In fertilizer production Calcium oxide / phosphorus oxide content
In fertilizer production Molar ratio of sodium to phosphorus In brine Calcium magnesium (hardness) content
Total amount of EDA in brine In brine chloride content
In process liquid Chlorate / hydrogen peroxide / sulfuric acid content
In process liquid Phosphite / hypophosphite content
Ammonium ion / hydroxylamine in process liquid content
In the production of deionized water Sodium ion content
In the production of deionized water Silicon ion content